Chemical and Biochemical Engineering Homework Solutions
Problem
#5989

Activation Energy from Temperature and Rate Constant Data

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The decomposition of NO2 follows a second order rate equation. Data at different temperatures are as follows:
T (K)                   592      603 627 651.5        656
k (cm3/gmol.sec) 522      755 1700 4020 5030
Compute the energy of activation Energy from the data. The reaction is 2NO2 ---> 2NO + O2

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Problem CRE1.doc
Problem:

The decomposition of NO2 follows a second order rate equation. Data at
different temperatures are as follows:

T (K) 592 603 627 651.5 656

k (cm3/gmol.sec) 522 755 1700 4020 5030

 2NO + O2

Solution Summary

In this problem Activation Energy has been detemined by graphical method.

Solution
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