Chemistry Homework Solutions
Problem
#11548

Determine concentrations in mixture using determinants in EXCEL (correct attachment)

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Mixture of absorbing species.doc  View File

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Mixture of absorbing species.doc
A solvent called "mixed xylenes" contains the o-xylene, m-xylene,
p-xylene and ethyl

benzene. In the table below, the absorbances of each of the pure
components and the

absorbance of a sample of "mixed xylenes" were measured at four
different wavelengths.

All measurements used the same cell and, therefore, the same pathlength.
What is the

concentration of each compound? (Use the determinant function in EXCEL).

bX, assume X = 1

values of (molar
absorptivity)b

Wavelength(m) p-xylene m-xylene o-xylene ethylbenzene unknown

12.5 1.5020 0.0514 0.000 0.0408 0.1013

13.0 0.0261 1.1516 0.000 0.0820 0.09943

13.4 0.0342 0.0355 2.532 0.2933 0.2194

14.3 0.0340 0.0684 0.000 0.3470 0.03396


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