Chemistry Homework Solutions
Problem
#26783

Bonding and Molecule formation

A sample of solid monoprotic acid with molar mass equal to 192.3g/mol was titrated with 0.1237M sodium hydroxide solution. Calculate the mass in grams of acid to be used if the volume of NaOH to be used is 25mL.
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A sample of solid monoprotic acid with molar mass equal to 192.3 g/mol
was titrated with 0.1237 M sodium hydroxide solution. Calculate the mass
in grams of acid to be used if the volume of NaOH to be used is 25 mL.

Do not enter the units. Be sure to consider significant figures. If you
wish to use scientific notation, use the "e" format - eg. 7.31e4 = 73100
& 1.90e-2 = 0.0190





 

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What is the total number of non-bonding valence electrons in chlorine
nitrate, ClONO2?

(All O atoms bonded to N, Cl bonded to O)





a.

) 16  



b.

) 18  



c.

) 19  



d.

) 20  



e.

) 22  



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Which species has two lone pairs on the central atom?





a.

) BCl3  



b.

) PCl3  



c.

) XeF4  



d.

) SF4  



e.

) SF6  



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All of the following species contain only atoms with exactly full (2
electrons for H, 8 otherwise) valence shells except





a.

) CH3OH  



b.

) O2  



c.

) NH4+  



d.

) ClO2-  



e.

) BH3  

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Which of the following molecular species are best described using three
charge-minimized resonance structures? (The central atoms are
underlined)





a.

SF4  



b.

SO3  



c.

SO32-  



d.

HSO4-  



e.

SO2+  



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Which of the following statements are true regarding the Lewis
structures of N2O and NO2-?





a.

There are more than eight electrons in the valence shell of one of the
atoms in NO2-.  



b.

There are positive (+) formal charges in both of these species.  



c.

There are four bonds about one of the N atoms in N2O.  



d.

There are negative (-) formal charges in both of these species.  



e.

There are no lone pairs on either N in N2O.  



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H° for the reaction:

C2H5Cl(g) ---> HCl(g) + C2H4(g)

given the following bond energies in kJ/mol: C-C, 348; C-H, 414; C-Cl,
327; H-Cl, 431; C=C, 615





a.

) +43 kJ  



b.

) -305 kJ  



c.

) +109 kJ  



d.

) -43 kJ  



e.

) +305 kJ  

 

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H is the lattice energy of MgCl2(s)?





a.

) Cl2(g) + Mg(s) ---> MgCl2(s)  



b.

) MgCl2(s) ---> Mg(g) + 2Cl(g)  



c.

) Mg2+(g) + 2Cl-(g) --> MgCl2(s)  



d.

) MgCl2(s) ---> Mg2+(aq) + 2Cl-(aq)  



e.

) Mg(g) + 2Cl(g) --> Mg2+(g) + 2Cl-(g)  

 

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Based on ionic radii and charges which of the following solids would
have the smallest (magnitude) lattice energy?





a.

) CsBr  



b.

) LiF  



c.

) CaCl2  



d.

) CaO  



e.

) BaO  

 

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(g) = +844 kJ.

Enthalpy of sublimation of Ca (s) = 178 kJ.

First ionization energy of Ca (g) = 590. kJ.

Second ionization energy of Ca (g) = 1150. kJ.

Standard enthalpy of formation of CaO (s) = - 635 kJ.

Trailing zeros should be considered significant.

Do not enter your answer with scientific notation.



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