Question 1 (.8 points)
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Find the false statements about oxides, as investigated in the
laboratory:
i) MgO dissolved in an acid, proving it is a basic oxide.
ii) Lithium hydroxide was formed when metallic lithium reacted with
water.
iii) Yellow sulfur burned in oxygen, producing a basic oxide.
iv) Dissolving copper oxide in sulfuric acid produced hydrogen gas.
v) Since phosphorus is a nonmetal, it forms an acidic oxide.
e. i, ii, v
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Question 2 (.8 points)
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In a thermochemistry experiment the reaction of 0.0857 g of an unknown
metal and an excess of 4.0 M HCl resulted in a 0.210 mL decrease in the
volume of an ice/water mixture. Calculate the enthalpy of this reaction
per 1 g of metal reacted. Needed data:
density of water at 273 K = 1.00 g/ml
density of ice at this temperature = 0.917 g/mL
ice enthalpy of fusion = 333 J/g
e. +0.723 kJ
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Question 3 (.9 points)
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Arrange the following pure substances in order of increasing molar
entropy at 298 K:
(1) acetone, (2) carbon monoxide, (3) methanol, (4) sodium acetate.
e. 2 < 4 < 3 < 1
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Question 4 (.9 points)
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When the equilibrium constant constant K at 25oC for
CO(g) + H2O(g) = H2(g) + CO2(g)
is calculated using data from Appendix B of Silberberg, the value
obtained is
e. ) 3.4 x 1059
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Question 5 (.8 points)
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A certain amount of heat, 5.21 kJ, is released during the reversible
freezing of one mole of a substance at a constant temperature of -8.72
oC. Calculate the entropy change of the substance associated with the
freezing process (in J/mole/K, with three significant figures). Do not
enter the units. Think about the sign!
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Question 6 (.9 points)
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Which of the following processes is (are) spontaneous at P = 1atm?
e. Ba2+(aq) + SO42-(aq) BaSO4(s) + H2O at 25oC.
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Question 7 (.8 points)
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Calculate Sfor the combustion of propane.
C3H8(g) + 5O2(g) 3CO2(g) + 4H2O(g)
Substance C3H8(g) O2(g) CO2(g) H2O(g)
S(J/Kmol) 269.9 205.138 213.74 188.825
e. 877.5 J/K
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Question 8 (.8 points)
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G for the reaction of ammonia with fluorine.
2NH3(g) + 5F2(g) N2F4(g) + 6HF(g)
Substance NH3(g) F2(g) N2F4(g) HF(g)
G f (kJ/mol) -16.4 0 79.9 -275.4
e. none of the above
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Question 9 (.8 points)
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When the following redox equation is balanced with the smallest whole
number coefficients, what is the coefficient for chlorine gas?
KmnO4 + KCl + H2SO4 = MnSO4 + K2SO4 + H2O + Cl2
e. ) 10
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Question 10 (.8 points)
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Consider the following reaction:
2Bi(OH)3(s) + 3Sn(OH)3-(aq) + 3OH-(aq) = 2 Bi(s) + 3 Sn(OH)62-(aq).
Identify the matching pairs below.
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Question 11 (.8 points)
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Which is most easily reduced - under standard conditions?
d. ) Mn
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Question 12 (.9 points)
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Consider the electrochemical cell:
Cr | Cr(NO3)3(aq)|| NiSO4(aq) | Ni.
Identify the false statement(s):
e. The concentration of Cr3+(aq) decreases as the reaction proceeds.
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