Chemistry Homework Solutions
Problem
#4278

Acids/bases : fraction present in acidic form

Hi. Here's the problem:

"What fraction of an acetic acid/sodium acetate buffer (pka of acetic acid = 4.76) is present in the acidic form at pH = 5.20?"

The answer is worked out in the book, but I don't know how to do the first step.

Please see attached.

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fraction acid.doc
[H+] = 6.31 x 10–6

Ka + [H+] 1.74 x 10–5 + 6.31 x 10–6



= 6.31 x 10–6

1.74 x 10–5 + 6.31 x 10–6



= 6.31 x 10–6

23.7 x 10–6



= 6.31

23.7



= 0.26





I’m just confused about the first step.



First, how do you figure out the Ka when you’re only given the pka?



I know that pka = –log Ka, but I don’t know how to reverse that
equation.



And second, how do you figure out the [H+] when you’re only given the
pka and the pH?



Thank you!
Solution
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Yongfeng Li, PhD (IP) - 4.2/5
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