Chemistry Homework Solutions
Problem
#59824

Ozonolysis of alpha-terpinene

Ignore Structure A in the attached .jpg for this problem.  Use only structures C and B

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Alpha -Terpinene, C10H16, a terpene found in coriander oil, absorbs only two moles of hydrogen, forming p-menthane, C10H20.  Ozonolysis of Alpha -terpinene yields structure C in the attached .jpg; permanganate cleavage yields structure B.

1.  How many rings, if any, are in Alpha -terpinene?

2.  On the basis of the cleavage products C and B and the isoprene rule, what is the most likely structure for Alpha terpinene?

3. How do you account for the presence of the OH groups in structure B?

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