Chemistry Homework Solutions

What is the structure of the hydrocarbon?

A hydrocarbon was found to have a molecular weight of 80-85. A 10.02 mg sample took up 8.40 mL of H2 gas at 0 degrees C and 760 mm pressure. Ozonolysis yielded only two compounds shown in the attached .jpg. What is the structure of the hydrocarbon? See attached file for full problem description.

Ozonolysis of Myrcene

Myrcene, C10H16, a terpene, absorbs three moles of hydrogen to form C10H22. Upon ozonolysis myrcene yields the two compounds shown in the first attached .jpg (I5Q2a). 1. What structures for myrcene are consistent with the facts? 2. Based on the isoprene rule (naturally occurring terpenes are made up of isoprene segments) ...continues

Structure of Muscalure and the intermediates A and B.

Muscalure is the sex pheromone of the common housefly. On the basis of the following information (in the attached .jpg), give the structure of Muscalure and the intermediates A and B. See attached file for full problem description.

Conversion of nerol into alpha-terpinol - mechanism

Suggest a mechanism (using arrows/arrow pushing and intermediates if applicable) for the conversion of nerol (C10H18O) into alpha-terpineol (C10H18O) in the presence of dilute H2SO4 - see the attached .jpg for start and end products.

Writing a chemical equation for the conversion of Codeine to Morphine in the body

Writing a chemical equation for the conversion of Codeine to Morphine in the body. I know that the ether group of codeine becomes an alcohol group in the morphine, but I am unable to get a formula with the other products. I could also use some help with making sure I have the functional groups for morphine and codeine corre ...continues

8 questions (L3)

16. What properties should an ideal recrystallization solvent have? 17. What is meant by the term solvent pair when it is employed in reference to the recrystallization of solids? 18. What is the purpose of adding powdered charcoal to the solvent system during a recrystallization sequence? 19. Why d ...continues

2 Questions (L4)

1. Offer an explanation of why anthracene preferentially forms a Diels-Alder adduct at 9,10 positions. 4. Outline a synthetic reaction scheme for the preparation of triphenylmethanol from: a. Methyl benzoate b. Diethyl carbonate

4 questions (L4)

5. In the experiment, ligroin may be used as a solvent for the separation of the product from biphenyl. a. What is ligroin? b. Can you suggest an alternative solvent that might be used in this step? 9. Consider the same reaction as in the previous question (#8) except that in this case it is carried out with ethyl benzoa ...continues

3 Questions (L4)

13. Why it is important that any aldehyde used in Witting reaction be free of carboxylic acid impurities? 14. Explain why the C=C stretching mode gives rise to a rather weak IR band in 1-methylcyclohexane, while in its isomer, methylenecyclohexene, the band is of medium to strong intensity. 15. Predict the major organic ...continues

3 questions (L4)

6. Give the reaction scheme, showing the products formed (before hydrolysis), when one equivalent of ethylmagnesium bromide is treated with one equivalent of 5-hydroxy-2-pentanone. Does addition of two : equivalents of the Grignard reagent to this yield a different product(s)? If so, give structure(s). 7. Explain why Grig ...continues

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