Chemistry Homework Solutions

sublimation

The vapor pressures of 1,2-diphenylethane, p-dichlorobenzene, and 1,3,5-trichlorobenzene are 0.06, 11.2, and 1.4 torr, respectively, at their melting point (52-54 degrees C). Which compound is likely to be sublimed most rapidly at a reduced pressure of 15 torr and a temperature of 40 degrees Celcius?

weight of water

Calculate the weight of water required to steam distill 500mg of bromobenzene at 95 degrees Celsius. the vapor pressure of water at this temperature is 640 torr, bromobenzene is 120 torr.

how to determine a limiting reagent and percent yield

how to determine a limiting reagent and percent yield

bromination of trans-cinnamic acid

I recently did an experiment where the addition of bromine to trans-cinnamic acid gives a dibromide with two stereocenters (chiral centers). Thus, there were four stereoisomers possible (see figures on page 136 on attachment). According to the melting points of my product, I ended up with the racemic mixture (2R,3S) and (2S, ...continues

Reactions

What product would you expect to obtain from the reaction of one equivalent of propanol with phthalic anhydride?

Mechanisms

Write a suitable mechanism for the cleavage of butyl isopropyl ether with HI at 100 degrees Celsius to form exclusively isopropyl alcohol and 1-iodobutane. Explain why butyl alcohol and isoproplyl iodide are not formed in the reaction.

Products

What product would you expect to form when tetrahydrofuran is treated with excess hydroiodic acid(HI)?

Nitration

Ferrocene cannot be nitrated using the conventional HNO3-H2SO4 mixed acid conditions, even though nitration is an electrophilic aromatic substitution reaction. Explain

Structures

If 3-bromo-1-propanol is treated with NaOH, a compound of molecular formula C3H6O is formed. Suggest a structure for this product.

equation

Write an equation for the reaction of phthalimide with potassium amide in N,N-dimethyl formamide(DMF) solvent. Name the product.

Browse