Chemistry Homework Solutions

Products

Predict the major organic product formed in the following reaction: CH3CH2NO2 + CH2O

Hydrocarbons

What hydrocarbon would you expect to obtain by the action of water on each of the Grignard reagents listed below? (a) Butylmagnesium bromide (b) sec-Butylmagnesium bromide (c) iso-Butylmagnesium bromide (d) tert-Butylmagnesium bromide

Grignard reagent

It is likely that the amount of Grignard reagent your analysis indicates is greater than the amount of Grignard reagent actually present just before you added water. Explain

Reactions

Indicate the product of the following reactions and name the organometallic product: 4CH3MgCl + SiCl4 -----> ??? 2C6H5MgCl + HgCl2 ----> ???

balanced equations

In preparation of esters given in an experiment, the reaction product was extracted with 5% sodium bicarbonate solution(NaHCO3) in the isolation step. Why? What gas was evolved during this washing step? Write the balanced equation for the reaction that produced it.

Structures

Draw the structures of the two fatty acids below and determine their common name Hexadecanoic acid Octadecanoic acid

Specific Rotation - A sample of 150 mg of an rganic compound is dissolved in 7.5 mL of water. The solution is placed in a 20-cm polarimeter tube and the rotation measured in a polarimeter. The rotation observed was +2.676 degrees. Distilled water in the same tube gave a reading of +0.016 degrees. Calculate the specific rotation for the compound.

A sample of 150 mg of an rganic compound is dissolved in 7.5 mL of water. The solution is placed in a 20-cm polarimeter tube and the rotation measured in a polarimeter. The rotation observed was +2.676 degrees. Distilled water in the same tube gave a reading of +0.016 degrees. Calculate the specific rotation for the compound ...continues

Meso Form

Which of the following have a meso form? 2,3-Dibromopentane 2,4-Dirbromopentane 2,3-Dibromobutane

NMR / IR spectrum

How many peaks would you expect to find in the NMR spectrum of caffeine? What characteristic absorption bands would you expect to find in the Infrared Spectrum of caffeine?

Distillate

Explain why the distillate collected from the steam distillation of cinnamon is cloudy.

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