Chemistry Homework Solutions

SDS-PAGE electrophoresis, and isoelectric focusing

1) Considering the SDS gel results, is mutant I a result of an exchange of one amino acid for another or loss or gain of one or more amino acids? 2) Considering the SDS gel results, is mutant II a result of an exchange of one amino acid for another or a loss or gain of one or more amino acids? 3) Considering the IEF gel result ...continues

Acid -base properties of a salt

(a) Identify the acidic hydrogen atom in the structure above. (b) In one stage of purification, the organic extract of the crude penicillin G is treated with a buffer solution at pH = 6.50. What is the ratio of P- to HP at this pH? (c) Penicillin G is not suitable itself for oral administration, but the sodium salt NaP ...continues

solubility

Calculate Solubility for Calcium Fluoride in 0.050 m (molality). Compare to the Solubility found ideally. Ksp for Calcium fluoride =3.9 x 10^-11. I need to find this number using activity coeffecients and ionice strength.

Standard free energy

Can you look over my solutions and let me know if the process is correct. I'm not 100% sure. Calculate the ratio of [glutamine]/[glutamate] at equilibrium.

Enthalpy, entropy and gibbs free energy.

Can you take a look at the solutions for the attached problem. It seems trivial, but there is some points that I feel am missing (re:pressure range). See attached file. Thanks

Conc. of an ideal solution as function of T and position in a strong gravit. field

An ideal solution w solute density 1.05 and solvent density 1.00 is subject to a huge gravity force field, a linear function of postition, F=kr, k is a constant and r is the position along the field. Derive the concentration as a function of T and position r along the field. (Hints: express grav. potential as function of r, Gi ...continues

thermodynamics: H, U

For any isothermal change of state in an ideal gas, how is the relation "delta H = delta U" derived?

Adiabatic expansion

0.5 mol of an adiabatic monotonic ideal gas in a container at 250kPa and 350K is allowed to expand: a) reversibly b) against a constant pressure of 150kPa until a final pressure of 150kPa is reached. Find the final temperature, delta U, delta H, q, and w for each process (a & b).

Adiabatic expansion

0.5 mol of an adiabatic monotonic ideal gas in a container at 250kPa and 350K is allowed to expand reversibly: Cv= (3/2)R Cp= (5/2)R If possible, find the final temperature, delta H, delta U, q, and w

Adiabatic ideal gas expansion @ constant pressure

0.5 mol of an adiabatic monotonic ideal gas in a container at 250kPa and 350K is allowed to expand against a constant pressure of 150kPa until a final pressure of 150kPa is reached. (Cv=3/2R, Cp= 5/2R) if possible, find the final temperature, delta H, delta U, q, and w.

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